That doesn't sound good at all. In fact, 4.2 should be possible with the stock cooler without getting temps like that - let alone with a third party HSF. Looking around, it seems that load temperature at 4.2 using the 212 should be more around 65C. In any case, it would be most unwise to allow temps to go over 80C - personally, I get uncomfortable at anything over 75C.
A few questions...
What software are you using to measure your temperatures? AI Suite is carp.
CoreTemp is better.
What temperatures were you getting before overclocking?
How have you set up your overclock? Have you just used the autotune thing from within AI Suite? That is not generally a good option since it can result in excessive voltage causing high temperatures. That said, even on auto, an overclock of 4.2 should not result in voltages getting up high enough to cause those levels of temperatures.
Did you remove the plastic film from the bottom of the new HSF? Perhaps a silly question but it is not unknown for that to be forgotten

What paste have you used and how was it applied? Did you remove the old paste from the CPU before installing the new HSF?
Are the fans spinning properly? Looking at AI Suite, what speed do the fans get to when at load? Are they plugged into the correct socket on the motherboard (probably CPU_FAN)?
Personally, I would remove the HSF. Clean the CPU. Clean the HSF. Re-apply paste using whatever instructions came with the HSF. Re-install the HSF using as much pressure as is possible. Then see what happens.
[edit] just realised that I have written the above assuming you have an ASUS motherboard - not sure why! For any other brand of motherboard, replace my comments about AI Suite with whatever software came with the board!
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